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Regular paprika is not necessarily the product of one specific chile but rather, can be a combination of several different peppers that meet the correct heat and color requirements. It usually comes from New Mexico, California, Hungary, or South America.
However, all cayennes have one thing in common: They’re spicy.

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8. CHILI POWDER
So, how can you substitute chili powder for paprika? Well, I can't really give you a standard substitution ratio. It's best to add it gradually, give your recipe a taste, and then adjust accordingly.
Chipotle powder is probably the best smoked paprika substitute on your spice rack. Like the original ingredient, this replacement is also considered mildly spicy with a heat level that ranges from 2,500 to 8,000 Scoville Heat Unit (SHU) on the Scoville Scale. Made from smoked dried jalapeño peppers, this spice is also known for its remarkable smoky and earthy taste — the result of the smoking process. Its bright red color also closely resembles paprika. All things considered, the chipotle powder is a fantastic backup for smoky dishes rather than spicy recipes.
So, how do you use crushed red pepper flakes to substitute for paprika in your recipes? You will need to add one-third of the amount to the same amount of paprika required in your recipe.